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Catalytic hydrolysis of gaseous HCN over CuNi/γ-Al

Linxia Yan, Senlin Tian, Jian Zhou, Xin Yuan

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 6, doi: 10.1007/s11783-016-0872-8

Abstract: The CuNi/γ-Al O catalyst was prepared to study HCN hydrolysis ?decreases NH production GRAPHIC ABSTRACT To decompose efficiently hydrogen cyanide (HCN) in exhaust gas, g-AlO -supported bimetallic-based CuNi catalyst was prepared by incipient-wetness impregnation method.volume ratio, reaction temperature, and the presence of CO or O on the HCN removal efficiency on the CuNi/g-Al O catalyst were investigated.

Keywords: Hydrogen cyanide     CuNi/g-Al<sub>2sub>O<sub>3sub>     Catalytic hydrolysis    

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2,   Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnationThe presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomerationdue to improved Ni dispersion and weakened interactions between the nickel species and the support.Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-NiThe co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the

Keywords: Mn promotion     nickel catalysts     CO<sub>2sub> methanation     co-methanation of CO and CO<sub>2sub>    

A Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 6, doi: 10.1007/s11783-021-1425-3

Abstract:

Cu<sub>0.15sub>-ACF performs the best for H<sub>2sub>S and PH<sub>3sub> simultaneous removal.

Keywords: ACF     H<sub>2sub>S     PH<sub>3sub>     Cu     Low temperature     Simultaneous removal    

Preparation of Cu/ZnO/Al

Hui FAN, Huayan ZHENG, Zhong LI

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 4,   Pages 445-451 doi: 10.1007/s11705-010-0521-x

Abstract: Cu/ZnO/Al O catalysts with Cu/Zn/Al ratios of 6/3/1 were precipitated and aged by conventional and microwavemicrowave irradiation on the catalytic performance was investigated to optimize the preparing condition of Cu

Keywords: microwave irradiation     precipitation temperature     aging temperature     methanol synthesis     Cu/ZnO/Al<sub>2sub>O<sub>3sub> catalyst    

An investigation of the CHOH and CO selectivity of CO hydrogenation over Cu–Ce–Zr catalysts

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 950-962 doi: 10.1007/s11705-022-2162-2

Abstract: 2sub> to CO/CH<sub>3sub>OH products.The Cu–Ce–Zr catalyst with 2 wt% Ce loading shows higher CO selectivity (S<sub>COsub> = 0.0%At the CO<sub>2sub> adsorption step, a larger number of hydroxyl groups over the Cu–Ce–Zr catalystHence, the Cu–Ce–Zr catalyst with 8 wt% Ce loading favors CH<sub>3sub>OH selectivity and CO<sub>22sub> hydrogenation to CH<sub>3sub>OH.

Keywords: CO<sub>2sub> hydrogenation     Cu–Ce–Zr     hydroxyls     CO/CH<sub>3sub>OH selectivity    

Preparation of Cu/ZrO

Xinmei LIU, Shaofen BAI, Huidong ZHUANG, Zifeng YAN

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 1,   Pages 47-52 doi: 10.1007/s11705-011-1170-4

Abstract: Cu/ZrO catalysts for methanol synthesis from CO /H were respectively prepared by deposition coprecipitation

Keywords: Cu/ZrO<sub>2sub>     methanol synthesis     deposition coprecipitation     solid state reaction     CO<sub>2sub>/H<sub>2sub>    

Fe - Ni - Co - Al<sub>2sub>O<sub>3sub> Cermets Inert Anode for Aluminum Electrolysis

Qiu Zhuxian,Shi Zhongning,Xu Junli

Strategic Study of CAE 2004, Volume 6, Issue 8,   Pages 35-39

Abstract: The cell was built with a graphite cathode of 120 mm×40 mm×20 mm and a Fe - Ni - Co -Al<sub>2sub>O<sub>3sub> cermet inert anode of 120 mm×80 mm×15 mm.The purity of aluminum metal produced was 98%〜99%, the impurities were mainly Fe, Ni and Co.The anode gas consisted of 98%〜99% O<sub>2sub> which was analyzed with an Orsat apparatus.>2sub>O<sub>3sub> in the bath and the anode used was inert.

Keywords: aluminum electrolysis     inert anode     back EMF value    

Optimization of electrochemically synthesized Cu

Kasra Pirzadeh, Ali Asghar Ghoreyshi, Mostafa Rahimnejad, Maedeh Mohammadi

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 233-247 doi: 10.1007/s11705-019-1893-1

Abstract: Cu (BTC) , a common type of metal organic framework (MOF), was synthesized through electrochemical routeTaguchi method was employed for optimization of key parameters affecting the synthesis of Cu (BTC) .indicated that the optimum synthesis conditions with the highest CO selectivity can be obtained using 1 gof ligand, applied voltage of 25 V, synthesis time of 2 h, and electrode length of 3 cm.bar) was a considerable value of 4.40 mmol·g .

Keywords: Cu<sub>3sub>(BTC)<sub>2sub> electrochemical synthesis     CO<sub>2sub> adsorption     Taguchi optimization    

Research of the Preparation Technology for Zr<sub>66sub>Al<sub>9sub>Cu<sub>16sub>Ni<sub>9sub>

Ruan Xuping,Ruan Hongwei

Strategic Study of CAE 2004, Volume 6, Issue 5,   Pages 76-78

Abstract: The results showed that the compound oxide glass composed of B<sub>2sub>O<sub>3sub> and Na<sub>2sub>SiO<sub>3sub> reacted with some elements in the melt, therefore, it wasn´t favourable forcoating the Zr<sub>66sub>Al<sub>9sub>Ni<sub>9sub>Cu<sub>16sub> alloy, hence hindering the formationThe fluorides composed of CaF<sub>2sub>(45%), A1F<sub>3sub>(50% ) and CaO (5%) and frace Ti0<sub>sub>Al<sub>9sub>Ni<sub>9sub>Cu<sub>16sub> alloy.

Keywords: bulk amorphous alloy     preparation technology     glass     fused salt     vacuum degree    

Cu-doped Bi/Bi<sub>2sub>WO<sub>6sub> catalysts for efficient N<sub>2sub> fixation by photocatalysis

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1412-1422 doi: 10.1007/s11705-023-2312-1

Abstract: In this paper, Cu-doped Bi<sub>2sub>WO<sub>6sub> was synthesized via a solvothermal method and appliedThe doped Cu had a valence state of +2 and most likely substituted the position of Bi3+.The optimized NH<sub>3sub> generation rates of Bi/Cu-Bi<sub>2sub>WO<sub>6sub> reached 624 and 243μmol·L–1·g–1·h–1 under simulated solar and visible light, and these>2sub>-to-NH<sub>3sub> conversion.

Keywords: Bi<sub>2sub>WO<sub>6sub>     Cu doping     work function     photocatalytic N<sub>2sub> fixation     charge    

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords: Rh<sub>2sub>O<sub>3sub>     CePO<sub>4sub>     N<sub>2sub>O decomposition    

g-CN-coated MnO hollow nanorod cathode for stable aqueous Zn-ion batteries

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 2,   Pages 217-225 doi: 10.1007/s11705-022-2214-7

Abstract: Herein, superior α-MnO<sub>2sub>@g-C<sub>3sub>N<sub>4sub> was successfully prepared forstable zinc-ion batteries (ZIBs) cathode by introducing g-C<sub>3sub>N<sub>4sub> nanosheets.Compared with pure α-MnO<sub>2sub>, α-MnO<sub>2sub>@g-C<sub>3sub>N<sub>4sub> hasEven at 1 A·g–1, the α-MnO<sub>2sub>@g-C<sub>3sub>N<sub>4sub> still retains 100The α-MnO<sub>2sub>@g-C<sub>3sub>N<sub>4sub>-based cathode has the highest energy density

Keywords: α-MnO<sub>2sub> hollow nanorods     g-C<sub>3sub>N<sub>4sub>     heterojunction     aqueous Zn-ion    

>In situ growth of phosphorized ZIF-67-derived amorphous CoP/Cu<sub>2sub>O@CF electrocatalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1430-1439 doi: 10.1007/s11705-023-2320-1

Abstract: The intermediate product was phosphorized to obtain final electrocatalyst (CoP/Cu<sub>2sub>O@CF) withThe electrochemical measurement proved that CoP/Cu<sub>2sub>O@CF catalyst exhibited excellent HER activitywas only 62 mV with the Tafel slope of 83 mV·dec–1 at a current density of 10 mA·cm2d-band center of CoP downshifted after bonding with ZIF-67 and the Gibbs free energy (ΔGCu<sub>2sub>O@CF catalyst, which will act as

Keywords: CoP/Cu<sub>2sub>O@CF     electrocatalyst     phosphorization     HER     DFT    

Advances in Cost-Efficient Thin-Film Photovoltaics Based on Cu(In,Ga)Se<sub>2sub>

Michael Powalla, Stefan Paetel, Dimitrios Hariskos, Roland Wuerz, Friedrich Kessler, Peter Lechner, Wiltraud Wischmann, Theresa Magorian Friedlmeier

Engineering 2017, Volume 3, Issue 4,   Pages 445-451 doi: 10.1016/J.ENG.2017.04.015

Abstract:

In this article, we discuss the leading thin-film photovoltaic (PV) technology based on the Cu(In,Ga)Se<sub>2sub> (CIGS) compound semiconductor.

Keywords: Thin-film photovoltaics     Solar energy     Flexible     Cu(InGa)Se<sub>2sub>    

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al<sub>2sub>O<sub>3sub> with a small amount, wasintroduced into Pb/SiO<sub>2sub> catalyst in this study.It has been proved that Al<sub>2sub>O<sub>3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO<sub>2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O<sub>3sub> addition was also proposed.

Keywords: Pb/SiO<sub>2sub>     Al<sub>2sub>O<sub>3sub>     propane dehydrogenation     propene     stability    

Title Author Date Type Operation

Catalytic hydrolysis of gaseous HCN over CuNi/γ-Al

Linxia Yan, Senlin Tian, Jian Zhou, Xin Yuan

Journal Article

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

A Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction

Journal Article

Preparation of Cu/ZnO/Al

Hui FAN, Huayan ZHENG, Zhong LI

Journal Article

An investigation of the CHOH and CO selectivity of CO hydrogenation over Cu–Ce–Zr catalysts

Journal Article

Preparation of Cu/ZrO

Xinmei LIU, Shaofen BAI, Huidong ZHUANG, Zifeng YAN

Journal Article

Fe - Ni - Co - Al<sub>2sub>O<sub>3sub> Cermets Inert Anode for Aluminum Electrolysis

Qiu Zhuxian,Shi Zhongning,Xu Junli

Journal Article

Optimization of electrochemically synthesized Cu

Kasra Pirzadeh, Ali Asghar Ghoreyshi, Mostafa Rahimnejad, Maedeh Mohammadi

Journal Article

Research of the Preparation Technology for Zr<sub>66sub>Al<sub>9sub>Cu<sub>16sub>Ni<sub>9sub>

Ruan Xuping,Ruan Hongwei

Journal Article

Cu-doped Bi/Bi<sub>2sub>WO<sub>6sub> catalysts for efficient N<sub>2sub> fixation by photocatalysis

Journal Article

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

g-CN-coated MnO hollow nanorod cathode for stable aqueous Zn-ion batteries

Journal Article

>In situ growth of phosphorized ZIF-67-derived amorphous CoP/Cu<sub>2sub>O@CF electrocatalyst

Journal Article

Advances in Cost-Efficient Thin-Film Photovoltaics Based on Cu(In,Ga)Se<sub>2sub>

Michael Powalla, Stefan Paetel, Dimitrios Hariskos, Roland Wuerz, Friedrich Kessler, Peter Lechner, Wiltraud Wischmann, Theresa Magorian Friedlmeier

Journal Article

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Journal Article